Laws of Thermodynamics

Underlying principles that govern all energy changes.




First Law Statements:

- Energy is conserved.

- The energy of the universe is constant.

- The change in the energy of the universe is zero.

ΔEuniverse = 0

- The sum of energy changes in the system and surroundings is zero.

ΔEuniverse = ΔEsystem + ΔEsurroundings = 0


- For an isolated system:        ΔEsystem = 0

- For a closed system:        ΔEsystem = q + w

- For a closed system at constant volume with only PV work:

ΔEsystem = qv